青藏高原唐古拉多年冻土区冻融循环过程中的能量平衡特征   总被引：1，自引：1，他引：0  

刘艺阗  姚济敏  赵林  肖瑶  乔永平  史健宗 《冰川冻土》2021,43(4):1073-1082

青藏高原多年冻土区冻融循环过程对地表能量及其分配的影响研究相对较少,青藏高原唐古拉站多年冻土的实测资料,依据10 cm土壤温度划分浅层土壤冻融循环的各个阶段并结合能量闭合率、地表能量各通量等数据探讨浅层土壤冻融循环过程与地气间水热交换过程之间的影响。结果表明：浅层土壤冻融循环过程各阶段均受气候变化的影响,其融化过程起始时间提前同时冻结过程起始时间推后,完全融化阶段持续时间增加,且逐渐接近完全冻结阶段持续时间;在浅层土壤不同冻融状态下,能量闭合率差值较大,其中完全融化阶段能量闭合状况普遍好于完全冻结阶段;净辐射值在完全融化阶段高于完全冻结阶段,净辐射在完全冻结阶段主要转化为感热通量,在完全融化阶段主要转化为潜热通量,地表土壤热通量在完全融化阶段为正值,在完全冻结阶段为负值。  相似文献   

Inter‐laboratory Characterisation of Apatite Reference Materials for Chlorine Isotope Analysis     

Alicja Wudarska  Ewa S&#x;aby  Michael Wiedenbeck  Jaime D. Barnes  Magali Bonifacie  Neil C. Sturchio  Grard Bardoux  Frdric Couffignal  Johannes Glodny  Linnea Heraty  Timm John  Christof Kusebauch  Sathish Mayanna  Franziska D. H. Wilke  Ewa Deput 《Geostandards and Geoanalytical Research》2021,45(1):121-142

Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca₁₀(PO₄)₆(F,Cl,OH)₂ solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for ³⁷Cl/³⁵Cl homogeneity using SIMS followed by δ³⁷Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean ³⁷Cl/³⁵Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ³⁷Cl_SMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 10³δ³⁷Cl_SMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25.  相似文献   

不同地质建造类型的生态环境功能特征——以西昌地区为例     

张腾蛟  刘洪  欧阳渊  张景华  张振杰  李樋 《中国地质调查》2021,7(6):35-49

地质建造背景可以直接反映该地区的形成演化过程、物质组成和地理条件,直接或间接地影响基岩上的生态环境。小范围内生态环境效应由地质建造直接控制,再由不同的气候条件、人类活动进行改造。土壤中的营养元素基本继承于母岩,而气候条件和人类活动同样会对土壤的物理性质、化学性质形成扰动。以中国地质调查局生态地质调查工程之大凉山区生态地质调查项目为依托,以沉积建造特征、空间分布、大地构造属性等因素为基础,将西昌地区划分为11个地质建造单元。通过详细的野外调查和数据分析,对西昌地区不同地质建造单元进行研究,认为建造单元上的生态地质环境存在明显的差异性,地质建造背景直接制约了成土母质及土壤的物理化学性质,营养元素在成土母质和土壤之间的迁移存在明显的继承性。同时,不同的地质建造单元和不同的地理地貌特征共同决定了不同地质建造单元的生态功能属性。研究成果为下一步开展生态地质调查提供依据和思路。  相似文献   

环境水样中农药污染分析技术研究进展   总被引：2，自引：2，他引：0  

郭婕  张燕  胡振国  刘菲 《岩矿测试》2021,(1):16-32

随着农业集约化和城市化的推进,世界上大量水环境中农药残留量已超过规定的限值,水环境中农药污染问题受到社会各界的广泛关注。作为世界上最大的农药生产国和使用国,中国水环境中农药残留量远高于其他发达国家,已有研究表明在我国七个典型流域(长江、太湖、黄河、松花江、黑龙江、大运河和东江)中检测到19种农药,平均浓度范围为0.02～332.75ng/L。农药及其转化产物对生态环境和人体健康具有潜在威胁,水环境中农药残留的研究是水质评估中必不可少的组成部分,而靶向筛查难以检测未知农药及其转化产物。因此,环境中农药残留及其转化产物的非靶向筛查亟需完善。本文依据农药组分非靶向筛查的分析流程,对近五年水质样品中农药残留靶向及非靶向筛查方法进行综述,梳理了近年来国内外食品与水环境中农药残留限量的相关法律法规,对水环境中农药残留分析方法的研究进展进行概述;总结了液液萃取(LLE)、固相萃取(SPE)、固相微萃取(SPME)等样品前处理方法的特点,在这些方法中,固相萃取是农药非靶向筛查的主要前处理方法,具有良好应用前景。本文还探讨了分析仪器从色谱检测到色谱-质谱联用的发展趋势,多种高分辨率质谱的产生为农药非靶向筛查提供了多层次的分析需求;同时通过总结近年来农药筛查确证相关的指导标准、质谱数据库与多种鉴定方法,指出水环境中农药污染分析技术的发展趋势。  相似文献   

Hydrothermal alteration processes in the giant Dahutang tungsten deposit,South China: Implications from litho-geochemistry and mass balance calculation     

《China Geology》2021,4(2):230-244

The giant Dahutang tungsten (W) deposit has a total reserve of more than 1.31 Mt WO₃. Veinlet-disseminated scheelite and vein type wolframite mineralization are developed in this deposit, which are related to Late Mesozoic biotite granite. Four major types of alterations, which include albitization, potassic-alteration, and greisenization, and overprinted silicification developed in contact zone. The mass balance calculate of the four alteration types were used to further understanding of the mineralization process. The fresh porphyritic biotite granite has high Nb, Ta, and W, but low Ca and Sr while the Jiuling granodiorite has high Ca and Sr, but low Nb, Ta, and W concentrations. The altered porphyritic biotite granite indicated that the Nb, Ta, and W were leached out from the fresh porphyritic biotite granite, especially by sodic alteration. The low Ca and Sr contents of the altered Neoproterozoic Jiuling granodiorite indicate that Ca and Sr had been leached out from the fresh granodiorite by the fluid from Mesozoic porphyritic biotite granites. The metal W of the Dahutang deposit was mainly derived from the fluid exsolution from the melt and alteration of W-bearing granites. This study of alteration presents a new hydrothermal circulation model to understand tungsten mineralization in the Dahutang deposit.  相似文献   

Evaluation of the Residual Mass Fractionation in High-Precision Cr Isotopic Analysis with TIMS     

Tetsuya Yokoyama  Yusuke Ohkuma  Keiji Nishikawa  Koki Sumiya  Ikshu Gautam 《Geostandards and Geoanalytical Research》2023,47(2):415-435

The Cr isotope ratios of terrestrial and extra-terrestrial materials are emerging as one of the most important tracers in geosciences. Previous studies on Cr isotopic measurements using TIMS have found that there is residual Cr isotopic fractionation between the mass-fractionation-corrected ⁵³Cr/⁵²Cr and ⁵⁴Cr/⁵²Cr ratios, which may cause an offset of obtained ratios from the reference values. The residual fractionation was thought to be caused by the evaporation of Cr-oxide species during thermal ionisation, but the mechanism by which this residual fractionation could be reduced remained unclear. Here we revisit the issue of residual fractionation and propose that this problem can be alleviated by utilising W filaments instead of conventionally used Re filaments for Cr ionisation. Using W filaments, the formation of CrO⁺ was suppressed during heating as the filament temperature was ~ 100 °C lower than when Re filaments were used. In repeated measurement of a carbonaceous chondrite, the intermediate precisions of ⁵³Cr/⁵²Cr and ⁵⁴Cr/⁵²Cr ratios in the W filament runs were two to three times better than those of the Re filament runs. Therefore, the new finding of this study will be of key importance for future studies of Cr isotopes for terrestrial and extra-terrestrial materials.  相似文献   

Sources of Inaccuracy in Boron Isotope Measurement Using LA-MC-ICP-MS     

Jan Fietzke  Eleni Anagnostou 《Geostandards and Geoanalytical Research》2023,47(3):481-492

Laser ablation multi-collector-inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS) has become a valuable tool for the in situ measurement of the boron isotope composition of geological samples at high (tens to hundreds of μm) spatial resolution. That said, this application suffers from significant analytical challenges. We focus in this study on the underlying processes of two of the main causes for inaccuracies using this technique. We provide empirical evidence that not only Ca ions (Sadekov et al. 2019, Standish et al. 2019, Evans et al. 2021) but also Ar ions, that are reflected within the flight tube of the mass spectrometer, are the source for previously reported issues with spectral baselines. We also address the impact of plasma conditions on the instrumental mass fractionation as a source for matrix- and mass-load-related analytical biases. Comparing experimental data with the results of a dedicated release and diffusion model (RDM) we estimate that a close to complete (~ 97%) release of boron from the sample aerosol is needed to allow for consistently accurate LA boron isotope measurement results without the need for corrections.  相似文献   

三维激光扫描技术在复杂地质隧道岩体信息获取中的优化     

师海  白明洲  李丽  田岗  张云龙 《测绘工程》2015,(6)

为了更高效、高精度地获取岩体结构面信息,借助三维激光扫描技术,提出并建立一种基于Kriging算子和最小二乘法组合的点云插值方法。首先对获取的隧道点云数据利用单一的最小二乘法进行插值,并以此为基础,结合Kriging算子的适应度函数建立组合插值模型。在利用三维激光扫描仪已获取的某岩溶隧道的原始点云数据的基础上,运用组合模型进行插值处理,以此获取岩体结构面信息,并将组合方法得到的结果与单一的插值方法进行对比,发现组合方法插值效果较好,误差也较小。基于Kriging算法和最小二乘法结合的插值方法,在利用三维激光扫描技术获取岩溶隧道岩体几何信息—结构面产状的过程中能更加精确、全面,并可以用于岩体稳定性评价。  相似文献   

滦河流域碳、水循环和能量平衡遥感综合试验总体设计     

阎广建  赵天杰  穆西晗  闻建光  庞勇  贾立  张永光  陈德清  姚崇斌  曹志宇  雷永荟  姬大彬  陈良富  柳钦火  吕利清  陈镜明  施建成 《遥感学报》2021,25(4):856-870

始于20世纪80年代的系列大型遥感试验开始系统研究地表物质和能量交换过程,对遥感与地球系统科学研究的结合起到重要作用,但是尚无综合利用多源遥感数据解决碳、水、能量循环问题的有效方案。遥感科学国家重点实验室于滦河上游地区组织开展基础性、多学科、多尺度的"碳、水循环和能量平衡遥感综合试验"。本次试验面向地球系统科学对遥感观测的最新要求,以遥感如何服务地—气过程研究为关键科学问题,开展星—机—地多尺度遥感综合观测和地面测量,论证中国自主设计的碳、水、能量相关卫星的技术指标,基于大场景真实结构模拟和多尺度综合观测构建虚拟遥感试验场,验证全波段遥感机理模型和复杂地表辐射传输机理。核心试验区位于地势较为平坦的闪电河流域和地形复杂的小滦河流域。闪电河流域主要地类为农田和草地,开展的试验以水循环和能量平衡遥感综合观测为主。小滦河流域主要地类为森林和草地,以碳循环遥感综合观测为主。两个试验区都开展了系统性的多架次飞行试验,并同步开展地面全波段、主被动协同观测。特别设计了一次长达165 km的大跨度飞行试验,横跨两个试验区,包含了地表类型和海拔高度的逐渐过渡。从2017年的预实验开始,整个试验为期5年。基于科学目标驱动、开放、协作、共享的原则,本次试验吸引了10个大型国家科研项目,4个卫星计划团队,19家单位200人次参加,是中国主导的又一次具有明确科学目标的大型多学科交叉遥感综合试验。  相似文献   

基于傅里叶变换质谱的烃源岩成熟度评价方法及地质意义     

韩双彪  谢林丰  唐致远  李剑  王成善  Brian HORSFIELD 《地质学报》2023,97(5):1717-1721

<正>伴随非常规油气资源的勘探开发,油气资源开采的广度和深度进一步扩大,一定程度上缓解了我国油气供需矛盾、保障了我国能源安全,同时有力推动了能源结构战略转型。但同时也对能源地质研究工作提出了新的挑战。有机质成熟度是油气评价的重要参数之一,不同成熟阶段的有机质会对应产出不同成因、不同性质、不同质量的油气,如何准确评价沉积有机质成熟度是当前油气资源勘探开发工作的关键问题之一。前人在科研实践工作中从光学、化学、谱学等角度提出了适用条件各异的成熟度评价方法,在部分地质环境中获得了良好的应用效果,但已有的成熟度指标多受测定方法原理的制约导致其适用性不同程度受限(肖贤明等,2020),制约了油气资源的高质量勘探开发。  相似文献